Publications
27. Cobalt-Catalyzed Hyperpolarization of Structurally Intact Olefins Muhammad, S. R.; Greer, R. B.; Ramirez, S. B; Goodson, B. M.; Fout, A. R. ACS Catal. 2021, 11, 2011-2020.
26. Varying the secondary coordination sphere: synthesis of cobalt and iron complexes of a tripodal ligand featuring two hydrogen-bond donors or acceptors Ford, C. L.; Miller, T. J.; park, Y. J.; Iranmanesh, N.; Gray, D. L.; Fout, A. R. Inorg. Chem. 2020, 73, 2195-2208.
25. Cobalt-Catalyzed Ammonia Borane Dehydrogenation: Mechanistic Insight and Isolation of a Cobalt Hydride-Amidoborane Complex Nugent, J. W.; Garcia-Melchor, M.; Fout, A. R. Organometallics 2020, 39, 2917-2927.
24. Catalytic Perchlorate Reduction Using Iron: Mechanistic Insights and Improved Catalyst Turnover Drummond, M. J.; Miller, T. J.; Ford, C. L.; Fout, A. R. ACS Catal. 2020, 10, 3175-3182.
23. Characterization of Terminal Iron(III)-Oxo and Iron(III)-Hydroxo Complexes Derived from O2 Activation Gordon, Z.; Miller, T. J.; Leahy, C. A.; Matson, E. M.; Burgess, M.; Drummond, M. J.; Popescu, C. V.; Smith, C. M.; Lord, R. L.; Rodriguez-Lopez, J.; Fout, A. R. Inorg. Chem. 2019, 58, 15801-15811.
22. Electronic Ligand Modifications on Cobalt Complexes and Their Application toward the Semi-Hydrogenation of Alkynes and Para-Hydrogenation of Alkenes. Muhammad, S. R.; Nugent, J. W.; Tokmic, K.; Zhu, L.; Mahmoud, J.; Fout, A. R. Organometallics. 2019, 38, 3132-3138.
21. Synthesis and Characterization of (DIPPCCC)Fe Complexes: A Zwitterionic Metalation Method and CO2 Reactivity. Jackson, B. J.; Najera, D.; Matson, E. M.; Woods, T. J.; Bertke, J. A.; Fout, A. R. Organometallics. 2019. 38, 2943-2952.
20. Radical Rebound Hydroxylation Versus H-Atom Transfer in Non-Heme Iron(III)-Hydroxo Complexes: Reactivity and Structural Differentiation. Drummond, M. J.; Ford, C. L.; Gray, D. L.; Popescu, C. V.; Fout, A. R. J. Am. Chem. Soc. 2019, 141, 6639-6650.
19. 13C NMR Signal Enhancement Using Parahydrogen-Induced Polarization Mediated by a Cobalt Hydrogenation Catalyst. Tokmic, K.; Greer, R. B.; Zhu, L.; Fout, A. R. J. Am. Chem. Soc. 2018, 140, 14844-14850.
18. Simple Nickel Salts for the Amination of (Hetero)aryl Bromides and Iodides with Lithium Bis(trimethylsilyl)amide. Espinosa Martinez, G.; Nugent, J. W.; Fout, A. R. Organometallics. 2018, 37, 2941-2944.
17. Cobalt-Catalyzed and Lewis Acid-Assisted Nitrile Hydrogenation to Primary Amines: A Combined Effort. Tokmic, K.; Jackson, J. B.; Salazar, A.; Woods, T. J.; Fout, A. R. J. Am. Chem. Soc. 2017, 139, 13554-13561.
16. Synthesis and Characterization of Bidentate NHC-CAryl Nickel(II) Complexes: Isocyanide Insertion To Form NHC-η2-iminoacyl Complexes. Nugent, J.W.; Espinosa Martinez, G.; Gray, D. L.; Fout, A. R. Organometallics. 2017, 36, 2987-2995.
15. Insights into a Chemoselective Cobalt Catalyst for the Hydroboration of Alkenes and Nitriles. Ibrahim, A.D.; Entsminger S.; Fout, A. R. ACS Catal. 2017, 6, 3730–3734.
14. Tuning the Fe(II/III) Redox Potential in Nonheme Fe(II)−Hydroxo Complexes through Primary and Secondary Coordination Sphere Modifications. Gordon, Z.; Drummond, M. J.; Matson, E. M.; Bogart, J. A.; Schelter, E. J.; Lord, R. L.; Fout, A. R. Inorg. Chem. 2017, 56, 4852-4863
13. A bioinspired iron catalyst for nitrate and perchlorate reduction. Ford, C.; Park, Y. J.; Matson, E. M.; Gordon, Z.; Fout, A. R. Science 2016, 354, 741-743. Abstract Reprint Full Print
12. Alkyne Semihydrogenation with a Well-Defined Nonclassical Co–H2 Catalyst: A H2 Spin on Isomerization and E-Selectivity. Tokmic, K.; Fout, A. R. J. Am. Chem. Soc. 2016, 138, 13700-13705.
11. Well-Defined Cobalt(I) Dihydrogen Catalyst: Experimental Evidence
for a Co(I)/Co(III) Redox Process in Olefin Hydrogenation. Tokmic, K.; Markus, C.R.; Zhu, L.; Fout, A.R. J. Am. Chem. Soc. 2016, 138, 11907-11913.
10. A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes. Ibrahim, A.D.; Entsminger, S.W.; Zhu, L.; Fout, A.R. ACS Catal. 2016, 6 , 3589-3593.
9. Accessing Pincer Bis(carbene) Ni(IV) Complexes from Ni(II) via Halogen and Halogen Surrogates. Espinosa Martinez, G.; Ocampo, C.; Park, Y.J.; Fout, A.R. J. Am. Chem. Soc. 2016, 138, 4290-4293.
8. Monoanionic bis(carbene) pincer complexes featuring cobalt(I–III) oxidation states. Ibrahim, A. D.; Tokmic, K.; Brennan, M. R.; Kim, D.; Matson, E. M.; Nilges, M. J.; Berkte, J. A.; Fout, A. R. Dalt. Trans. 2016, 45, 9805-9811.
7. Synthesis and characterization of M(II) (M = Mn, Fe and Co) azafulvene Complexes and their X3− Derivatives. Matson, E.M.; Park, Y.J.; Bertke, J.A.; Fout, A.R. Dalt. Trans. 2015, 44, 10377-10384.
6. Exploring Mn–O bonding in the context of an electronically flexible secondary coordination sphere: synthesis of a Mn(III)–oxo. Park, Y.J.; Matson, E.M.; Nilges, M.J.; Fout, A.R. Chem. Commun. 2015, 51, 5310–5313.
3. Nickel(II) Pincer Carbene Complexes: Oxidative Addition of an Aryl C−H Bond to Form a Ni(II) Hydride. Matson, E. M.; Espinosa Martinez, G.; Ibrahim, A. D.; Jackson, B. J.; Bertke, J. A.; Fout, A. R. Organometallics. 2015, 34, 399-407.
5. Facile Nitrite Reduction in a Non-heme Iron System: Formation of an Iron(III)-Oxo. Matson, E.M.; Park, Y.J.; Fout A.R. J. Am. Chem. Soc. 2014, 136, 17398–17401.
4. Meridional vs. facial coordination geometries of a dipodal ligand framework featuring a secondary coordination sphere. Matson, E.M.; Gordon, Z.; Lin, B.; Nilges M.J.; Fout, A.R. Dalt. Trans. 2014, 43, 16992-16995.
2. A Synthetic and Mechanistic Investigation into the Cobalt(I) Catalyzed Amination of Aryl Halides. Brennan, M. R.; Kim, D.; Fout, A. R. Chem. Sci. 2014, 5, 4831-4839.
1. Isolation of Iron(II) Aqua and Hydroxyl Complexes Featuring a Tripodal H-bond Donor and Acceptor Ligand. Matson, E. M.; Bertke, J. A.; Fout, A. R. Inorg. Chem. 2014, 53, 4450-4458.
Dehydrogenation of hydrocarbons with metal-carbon multiple bonds and trapping of a titanium(II) intermediate. Hickey, A. K.; Crestani, M. G.; Fout, A. R.; Gao, X.; Chen, C.-H.; Mindiola, D. J. Dalton. Trans. 2014, 43, 9834-9837.
Synthesis of Open-Shell, Bimetallic Mn/Fe Trinuclear Clusters. Powers, T. M.; Gu, N. X.; Fout, A. R.; Alfonso, D. M.; Chen, Y.-S.; Zheng, S.-L.; Betley, T. A. J. Am. Chem. Soc. 2013, 135, 1448-14458.
Understanding intermolecular C−F bond activation by a transient titanium neopentylidyne: experimental and theoretical studies on the competition between 1,2-CF bond addition and [2+2]-cycloadditon/β-fluoride elimination. Fan, H.; Fout, A. R.; Bailey, B. C.; Pink, M.; Baik, M.-H.; Mindiola, D. J. Dalton Trans. 2013, 42, 4163-4174.
Trigonal Mn3 and Co3 Clusters Supported by Weak-Field Ligands: A Structural, Spectroscopic, Magnetic and Computational Investigation into the Correlation of Molecular and Electronic Structure. Fout, A. R.; Xiao, D. J.; Zhao, Q.; Harris, T. D.; King, E. R.; Eames, E. V.; Zheng, S.-L.; Betley, T. A. Inorg. Chem. 2012, 51, 10290-10299.
1,2-CF bond activation of perfluoroarenes and alkylidene isomers of titanium. DFT analysis of the C−F bond activation pathway and rotation of the titanium alkylidene moiety. Andino, J. G.; Fan, H.; Fout, A. R.; Bailey, B. C.; Baik, M.-H.; Mindiola, D. J. J. Organomet. Chem. 2011, 696, 4138-4146.
Oxidative Group Transfer to a Trimanganese Complex to Form an Interstitial μ6-nitride and μ6-oxide, [Mn6(μ6-E)]n-. Fout, A. R.; Zhao, Q.; Xiao, D. J.; Betley, T. A. J. Am. Chem. Soc. 2011, 133, 16750-16753.
1,2-CF Bond Activation of Perfluoroarenes and Alkylidene Isomers of Titanium. DFT Analysis of the C-F Bond Activation Pathway and Rotation of the Titanium Alkylidene Moiety. Andino, J. G.; Fan, H.; Fout, A. R.; Bailey, B. C.; Baik, M.-H.; Mindiola, D. J. J. Organomet. Chem. 2011, 696, 4138-4146
Atom Economical Route to Substituted Pyridines via a Scandium Imide. Wicker, B. F.; Scott, J. L.; Fout, A. R.; Pink, M.; Mindiola, D. J. Organometallics. 2011, 30, 2453-2456.
Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ3-Nitride [Fe3(μ3-N)]-. Powers, T. M.; Fout, A. R.; Zheng, S.-L.; Betley, T. A. J. Am. Chem. Soc. 2011, 133, 3336-3338.
Synthetic and Mechanistic Studies of the Ring-opening and Denitrogenation of Pyridine and Picolines by a Ti-C Multiple Bond. Fout, A. R.; Buck, D. M.; Bailey, B. C.; Fan, H.; Huffman, J. C.; Baik, M.-H.; Mindiola, D. J. Organometallics. 2010, 29, 5409-5422.
Dehydrofluorination of Fluorohydrocarbons by Titanium Alkylidynes via Sequential C-H/C-F Bond Activation Reactions. A Synthetic, Structural, and Mechanistic Study of 1,2-CH Bond Addition and β-Fluoride Elimination. Fout, A. R.; Scott, J.; Miller, D. L.; Bailey, B. C.; Huffman, J. C.; Pink, M.; Mindiola, D. J. Organometallics. 2009, 28, 331-347.
Lewis Acid Stabilized Methylidene and Oxoscandium Complexes. Scott, J.; Fan, H.; Wicker, B. F.; Fout, A. R.; Baik, M.-H.; Mindiola, D. J. J. Am. Chem. Soc. 2008, 130, 14438-14439.
A Transient V(III)-Alkylidene Complex: Oxidation Chemistry Including the Activation of N2 to Afford a Highly Porous Honeycomb-like Framework. Kilgore, U. J.; Sengelaub, C. A.; Pink, M.; Fout, A. R.; Mindiola, D. J. Angew. Chemie, Int. Ed. 2008, 47, 3769-3772.
Evidence for the Existence of a Terminal Imidoscandium Complex. Intermolecular C-H Activation and Trapping Reactions with the Transient Sc=NAr Linkage. Scott, J.; Basuli, F.; Fout, A. R.; Huffman, J. C.; Mindiola, D. J. Angew. Chemie. Int. Ed. 2008, 47, 8502-8505.
The Progression of Synthetic Strategies to Assemble Titanium Complexes Bearing the Terminal Imide Group. Fout, A. R.; Kilgore, U. J.; Mindiola, D. J. Chem. Eur. J. 2007, 13, 9428-9440.
Cyclic Denitrogenation of N-Heterocycles Applying a Homogenous Titanium Reagent. Fout, A. R.; Bailey, B. C.; Tomaszewski, J.; Mindiola, D. J. J. Am. Chem. Soc. 2007, 129, 12640-12641.
An Alkylidyne Analogue to Tebbe's Reagent. Trapping Reactions of a Titanium Neopentylidyne by Incomplete and Complete 1, 2-Additions. Bailey, B. C.; Fout, A. R.; Fan, H.; Tomaszewski, J.; Huffman, J. C.; Mindiola, D. J. Angew. Chemie. 2007, 46, 8246-8249.
Snapshots of an Alkylidyne for Nitride Triple-Bond Metathesis. Bailey, B. C.; Fout, A. R.; Fan, H.; Tomaszewski, J.; Huffman, J. C.; Gary, J. B.; Johnson, M. J. A.; Mindiola, D. J. J. Am. Chem. Soc. 2007, 129, 2234-2235.
A Co2N2 Diamond Core Resting State of Cobalt (I): A Three-Coordinate Co(I) Synthon Invoking an Unusual Pincer-Type Rearrangement. Fout, A. R.; Basuli, F.; Fan, H.; Tomaszewski, J.; Huffman, J. C.; Baik, M-H.; Mindiola, D. J. Angew. Chemie. 2006, 45, 3291-3295.
Titanium Complexes Supported by a Sterically Encumbering N-anchored Tris-arylphenoxide Ligand. Cortes, S. A.; Munoz Hernandez, M. A.; Nakai, H.; Castro-Rodriguez, I.; Meyer, K.; Fout, A. R.; Miller, D.L.; Huffman, J. C.; Mindiola, D. J. Inorg. Chem. Comm. 2005, 8, 903-907.
Manganese(I) Poly(mercaptoimidazolyl)borate Complexes: Spectroscopic and Structural Characterization of Mn···H-B Interactions in Solution and in the Solid State. Graham, L. A.; Fout, A. R.; Kuehne, K. R.; White, J. L.; Mookherji, B.; Marks, F. M.; Yap, G. P. A.; Zakharov, L. N.; Rheingold, A. L.; Rabinovich, D. Dalton Trans. 2005, 1, 171-180.